Reduction of CO 2 by Pyridine Monoimine Molybdenum Carbonyl Complexes: Cooperative Metal–Ligand Binding of CO 2
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Reduction of CO2 by Pyridine Monoimine Molybdenum Carbonyl Complexes: Cooperative Metal-Ligand Binding of CO2.
[((Ar) PMI)Mo(CO)4 ] complexes (PMI=pyridine monoimine; Ar=Ph, 2,6-di-iso-propylphenyl) were synthesized and their electrochemical properties were probed with cyclic voltammetry and infrared spectroelectrochemistry (IR-SEC). The complexes undergo a reduction at more positive potentials than the related [(bipyridine)Mo(CO)4 ] complex, which is ligand based according to IR-SEC and DFT data. To pr...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2015
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201500463